Surface Ozone Measurements from a Global Network

From a network of sites, primarily in the Atlantic and Pacific Ocean regions, measurements of the surface ozone concentration yield information on the seasonal, synoptic, and diurnal patterns. These sites, generally removed from the effects of local pollution sources, show characteristics that typify broad geographical regions. At Barrow, AK; Mauna Loa, HI; American Samoa; and South Pole, data records of 15-20 years show trends that in all cases are a function of season. This dependence on season is important in understanding the causes of the long-term changes. At Barrow, the summer (July, August, September) increase of 1.7% per year is probably indicative of photochemical production. At South Pole, on the other hand, the summer (December, January, Ftbruary) decrease is related to photochemical losses and enhanced transport from the coast of Antarctica. At all the sites there is a pronounced seasonal variation. In the Southern Hemisphere (SH), all locations which run from 14 to 900S show a winter (July-August) maximum and summer minimum. In the Northern Hemisphere (NH) most of the sites show a spring maximum and autumn minimum. At Barrow (700N) and Barbados (141, however, the maxima occur during the winter, but for very different reasons. At many of the sites, the transport changes associated with synoptic scale weather patterns dominate the day-to-day variability. This is particularly pronounced at Bermuda and the more tropical sites. In the tropics, there is a very regular diurnal surface ozone cycle with minimum values in the afternoon and maxima early in the morning. This appears to result from photochemical destruction during the day in regions with very low concentrations of nitrogen oxides. At Niwot Ridge, CO, and Mace Head, Ireland, there is clear evidence of photochemical ozone production in the summer during transport from known regional pollution sources. Key II'ord index: Ozone distribution, ozone trends, surface ozone, tropospheric chemistry.